Deleting Structure Relationships
...
1.
From the selection
list of steps, choose Maintain Structure Relations.
A screen appears.
2. Position the cursor on the corresponding line.
3.
Choose Delete relationship.
The system deletes the corresponding structure relationship between both
systems.

When you delete a structure relationship, it is not possible to establish any relationships between the associated source fields and the SAP target fields. Field relationships already established will be deleted automatically.