Posting to Customer and Vendor Accounts 
Use
When posting to expenses and payables accounts, the G/L account is always derived from the symbolic account, and, if necessary, from the Employee Grouping for Account Determination.
When posting to customer and vendor accounts, you have two possibilities for controlling account determination:

It is not possible to use the special general ledger indicator when posting to customer and vendor accounts.
See also:
Example: Posting to Customer Accounts for Employees
Assign Customer Accounts
Assign Vendor Accounts
Assign Customer Accounts for Loan-Specific PostingPrerequisites
You have made the necessary settings in Payroll Customizing, under ® Reporting for Posting Payroll Results to Accounting ® Activities in AC System ® Assign Accounts.