Definition
You should only edit the profiles from the R/3 System using the CCMS profile maintenance tool. The advantages of profile maintenance over the conventional method of working - direct editing at operating system level using an editor - are:

You should only edit operating system files using an editor in exceptional cases. It only makes sense to do this if the R/3 System cannot be started in any other way.
See also:
Where Do Profiles Come From? Preparations for Profile Maintenance When Must Profiles be Maintained? Maintaining Profiles from the CCMS